(E)-Methyl N′-[1-(4-hydroxyphenyl)ethylidene]hydrazinecarboxylate
نویسندگان
چکیده
The title compound, C(10)H(12)N(2)O(3), adopts a trans configuration with respect to the C=N bond. The dihedral angle between the benzene ring and the hydrazine carboxylic acid plane is 8.29 (7)°. Mol-ecules are linked into a three-dimensional network by N-H⋯O, O-H⋯O, O-H⋯N hydrogen bonds and C-H⋯π inter-actions.
منابع مشابه
(E)-Methyl N′-[1-(2-hydroxyphenyl)ethylidene]hydrazinecarboxylate
The mol-ecule of the title compound, C(10)H(12)N(2)O(3), adopts a trans configuration with respect to the C=N bond. The dihedral angle between the benzene ring and the hydrazinecarboxyl-ate plane is 8.98 (7)°. Intra-molecular O-H⋯N and C-H⋯N hydrogen bonds are observed. Mol-ecules are linked into chains along the c axis by N-H⋯O hydrogen bonds. In addition, C-H⋯π inter-actions are observed.
متن کامل(E)-Ethyl N′-[1-(2-hydroxyphenyl)ethylidene]hydrazinecarboxylate
In the mol-ecule of the title compound, C(11)H(14)N(2)O(3), the dihedral angle between the benzene ring and the hydrazinecarboxyl-ate mean plane is 3.65 (12)°. Intra-molecular C-H⋯N and O-H⋯N hydrogen bonds result in the formation of a nearly planar six-membered ring, which is oriented at a dihedral angle of 2.38 (3)° with respect to the benzene ring, and a five-membered ring having an envelope...
متن کامل(E)-Methyl N′-[1-(4-methylphenyl)ethylidene]hydrazinecarboxylate
The title mol-ecule, C(11)H(14)N(2)O(2), adopts a trans configuration with respect to the C=N bond. The dihedral angle between the benzene ring and the hydrazinecarboxyl-ate plane is 7.61 (16)°. In the crystal structure, mol-ecules are linked into centrosymmetric dimers by N-H⋯O hydrogen bonds and the dimers are linked together by C-H⋯π inter-actions.
متن کاملMethyl (E)-N′-[1-(2,4-dihydroxyphenyl)ethylidene]hydrazinecarboxylate
The mol-ecule of the title compound, C(10)H(12)N(2)O(4), adopts a trans configuration with respect to the C=N bond. The dihedral angle between the benzene ring and the methyl hydrazinecarboxyl-ate plane is 3.01 (6)°. An intra-molecular O-H⋯N hydrogen bond is observed. In the crystal, mol-ecules are linked into a two-dimensional network parallel to (10) by O-H⋯O, N-H⋯O and C-H⋯O hydrogen bonds.
متن کامل(E)-Methyl N′-[1-(4-methoxyphenyl)ethylidene]hydrazinecarboxylate
The mol-ecule of the title compound, C(11)H(14)N(2)O(3), adopts a trans configuration with respect to the C=N bond. The dihedral angle between the benzene ring and the hydrazinecarboxyl-ate plane is 12.06 (9)°. Mol-ecules are linked into a one-dimensional network by N-H⋯O hydrogen bonds and C-H⋯π inter-actions. The benzene rings of inversion-related mol-ecules are stacked with their centroids s...
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عنوان ژورنال:
دوره 64 شماره
صفحات -
تاریخ انتشار 2008